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Asymmetric Epoxidation Of Dihydronaphthalene With A Synthesized Jacobsen's Catalyst
Beginning of paper
Asymmetric Epoxidation of Dihydronaphthalene with a Synthesized Jacobsen's
Chem 250 GG
Abstract. 1,2 diaminocyclohexane was reacted with L-(+)-tartaric acid to yield
(R,R)-1,2-diaminocyclohexane mono-(+)-tartrate salt. The tartrate salt was then
reacted with potassium carbonate and 3,5-di-tert-butylsalicylaldehyde to yield
(R,R)-N,N'-Bis(3,5-di- ....
Middle of paper
....naphthalene) to form an epoxide that is highly enantiomerically enriched,
as well as an oxidized byproduct.
Jacobsen's work is important because it presents both a reagent and a
method to selectively guide an enantiomeric catalytic reaction of industrial
and pharmacological importance. Very few reagents, let alone methods, are
known to be able .... |
| Word count: 2135 |
Page count: 8 |
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